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Educational Psychology Lesson Plans 181

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The first principles d. functional theory (DFT) approach (GGA-PW91/DNP) was used to study the addn. reaction of methylamine to fullerenes C50 and C60 or single-walled carbon nanotubes (SWNTs) (5,5) and (10,0). To understand the relationship between reactivity and curvature, various addn. sites have been investigated for comparisons. The DFT calcn. results showed that the reaction energy of the addn. of methylamine onto C60 or the closed caps of (5,5) and (10,0) is rather low. Moreover, the reaction at a few sites even appears exothermic. However, the reaction on the perfect sidewall of the nanotubes is always endothermic, and the reaction energy is much higher than that on the caps. The energetically preferable addn. sites are the carbon atoms located at the vertexes formed with five-, five-, six-membered rings on C50 or five-, five-, seven-membered rings on defects of nanotubes. The systematic theor. study revealed that the pyramidalization and π-orbital misalignment could result in an increased reactivity of these pentagon-pentagon fusion sites. The reactivity depends on the pyramidalization angle, which is a quant. measurement of the local curvature and strain of the reaction center. https://www.youtube.com/watch?v=m5pAL9-6940 https://kayelynnschwer1992.files.wordpress.com/2020/06/ebook-rolle-dich-schmerzfrei-9517.pdf • See more... https://feelingjullianna90.files.wordpress.com/2020/06/ebook-sex-mit-dem-frauenarzt-7258.pdf https://www.lexico.com/definition/tootle https://feelingjullianna90.files.wordpress.com/2020/06/ebook-stackpole-books-true-crime-pennsylvania-9366.pdf WHAT THE HELL?? Green tried to make his death sound LIKE HE WENT TO A PARTY LAST WEEK!!! 19 • - askscience


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